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Effect of crystallinity of pet bottle preform on its mechanical properties

Publish Time: 2024-11-11
The crystallinity of Pet bottle preform determines its mechanical properties to a large extent, and plays a key role in the performance of the bottle preform in subsequent processing and practical applications.

First, crystallinity is closely related to tensile strength. When the crystallinity of Pet bottle preform is within an appropriate range, its molecular chains are arranged more regularly and orderly, forming a crystal-like structural region. These crystallized areas can effectively share external forces, allowing the preform to exhibit high tensile strength when subjected to tensile force. For example, during the blow molding process, a Pet bottle preform with a certain degree of crystallinity can better resist tensile deformation and can be smoothly formed into a bottle with a specific shape and wall thickness to meet the needs of packaging products. However, if the crystallinity is too high, the movement of the molecular chains will be limited, and the material will become more brittle and hard, and will easily break when subjected to large impact forces, which will in turn reduce its overall mechanical properties.

Secondly, the degree of crystallinity also has a significant impact on the elastic modulus of the preform. Higher crystallinity will increase the elastic modulus of the Pet bottle preform, which means that the material deforms less when it is stressed. In practical applications, for example, for some beverage bottles that need to withstand a certain pressure, appropriate crystallinity can ensure that the bottle will not be excessively deformed due to internal pressure after containing liquid, and maintain the shape stability of the bottle. However, excessive crystallinity will cause the material to reduce elasticity and lack necessary flexibility. When subjected to repeated small external forces, micro-cracks may occur, thereby affecting the service life and safety of the preform.

Furthermore, the degree of crystallinity also affects the impact toughness of the preform. Moderate crystallization can improve the impact resistance of Pet bottle preform because the crystallized areas can absorb and disperse impact energy. But when the crystallinity is too high, the amorphous areas inside the material are relatively reduced, and these amorphous areas can originally dissipate energy through the slip and entanglement of molecular chains during the impact process. Too high crystallinity will weaken this The energy dissipation mechanism reduces the impact toughness of the preform, making it more susceptible to breakage and damage when subjected to accidental drops or collisions.

Finally, during the production process, precise control of the crystallinity of the Pet bottle preform is key to optimizing its mechanical properties. By adjusting the injection molding process parameters, such as temperature, pressure and cooling rate, the crystallinity can be effectively controlled, thereby obtaining a Pet bottle preform with good comprehensive mechanical properties, which can meet the requirements of bottle strength, toughness and stability in different packaging application scenarios. and many other requirements to ensure the reliability of products during storage, transportation and use.
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